Pulsed Dynamic Nuclear Polarization with Trityl Radicals
نویسندگان
چکیده
منابع مشابه
Polychlorinated trityl radicals for dynamic nuclear polarization: the role of chlorine nuclei.
Polychlorinated trityl radicals bearing carboxylate substituents are water soluble persistent radicals that can be used for dynamic nuclear polarization. In contrast to other trityl radicals, the polarization mechanism differs from the classical solid effect. DFT calculations performed to rationalize this behaviour support the hypothesis that polarization is transferred from the unpaired electr...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry Letters
سال: 2015
ISSN: 1948-7185
DOI: 10.1021/acs.jpclett.5b02720